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The octahedral tilting is uncovered to strongly influence the band hole values. The band hole improve, comparable to a blue change in the UV–vis absorption spectra, is proposed to become contributed with the octahedral tilting [93]. . expose the crystal alloying in Cs2AgBgBr6 with one at% Sn doping ranges (Sn@CS2AgBIBr6), ends in a bandgap re